Benzyl 3-[(E,E)-3-phenylprop-2-enylidene]dithiocarbazate
نویسندگان
چکیده
The title compound, C(17)H(16)N(2)S(2), a dithio-carbazate derivative, adopts an EE configuration with respect to the C=C and C=N double bonds of the propenyl-idine group. The 3-phenyl-prop-2-enyl-idene and dithio-carbazate fragments lie essentially in the same plane, with a maximum deviation from that plane of 0.074 (2) Å, while the dihedral angle between the 3-phenyl-prop-2-enyl-idene and the benzyl group is 77.78 (7)°. In the crystal structure, mol-ecules are linked by an N-H⋯S hydrogen bond and a weak C-H⋯S inter-action involving the terminal thione S atom, forming dimers that are arranged into sheets parallel to the bc plane. The crystal structure is also stabilized by C-H⋯π inter-actions.
منابع مشابه
Methyl 3-[(E,E)-3-phenylprop-2-enylidene]dithiocarbazate
In the title compound, C(11)H(12)N(2)S(2), the dithio-carbazate group adopts an EE configuration with respect to the C=C and C=N bonds of the propenyl-idene group. The atoms of the propenyl-idene and dithio-carbazate unit are essentially co-planar, with a maximum deviation of 0.058 (1) Å; the phenyl ring forms a dihedral angle of 18.3 (1)° with this fragment. In the crystal, mol-ecules form inv...
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